姓名：周雙六
性別：男
出生年月：
職稱：副教授
學(xué)院：化學(xué)與材料科學(xué)學(xué)院
研究方向：

所受教育
學(xué)士 （1995年） 安徽工程科技學(xué)院
碩士 （2003年） 安徽師范大學(xué)
博士 （2007年） 安徽師范大學(xué)

職稱職位
1995年-2000年 蕪湖永康食品廠助理工程師
2003年-現(xiàn)在 安徽師范大學(xué) 講師 副教授 碩士生導(dǎo)師
2007年-2009年 臺(tái)灣中興大學(xué)化學(xué)系博士后研究員

主持項(xiàng)目
外消旋稀土金屬有機(jī)配合物的控制性合成及其催化烯烴可控聚合研究，國(guó)家自然科學(xué)基金( 20802001)，2009-2011，項(xiàng)目主持人。
氮原子配位促進(jìn)稀土金屬-氮鍵均裂反應(yīng)研究，安徽省高校青年教師資助計(jì)劃（2004jq120），項(xiàng)目主持人，已結(jié)題。
新型含雜原子取代硅橋聯(lián)茚基稀土配合物的合成及其催化活性研究，安徽省教育廳自然科學(xué)基金項(xiàng)目（2005kj331zc），項(xiàng)目主持人，已結(jié)題。
新型硅橋聯(lián)茚基稀土配合物的合成及其催化活性研究，安徽師范大學(xué)青年基金（2005xqn14），項(xiàng)目主持人，已結(jié)題。
外消旋稀土金屬有機(jī)配合物的控制性合成及其催化烯烴的立體可控聚合研究，安徽師范大學(xué)博士啟動(dòng)基金，項(xiàng)目主持人。
新型連續(xù)稀土金屬-氮鍵斷裂/攫氧反應(yīng)研究，國(guó)家自然科學(xué)基金(20472001)，主要參加人。
鈀、銠、鎳催化活性丙烯?；陔x子液體中的選擇性成環(huán)偶聯(lián)反應(yīng)研究，國(guó)家自然科學(xué)基金（20572001），主要參加人。

研究領(lǐng)域
金屬有機(jī)化學(xué)
不對(duì)稱催化合成

講授課程
化工基礎(chǔ)
非金屬材料
應(yīng)化專業(yè)實(shí)驗(yàn)
綜合化學(xué)實(shí)驗(yàn)

獲獎(jiǎng)情況
蕪湖市首屆自然科學(xué)優(yōu)秀學(xué)術(shù)論文一等獎(jiǎng)，2004，第二完成人。

發(fā)表論文
Shuangliu Zhou, Chi-Ren Chen, Han-Mou Gau.* “Highly Enantioselective 3-Furylation of Ketones Using (3-Furyl)titanium Nucleophile” Org. Lett. 2010, 12, 48-51.
Shuangliu Zhou, Kuo-Hui Wu, Chien-An Chen, Han-Mou Gau*. “Highly Enantioselective Arylation of Aldehydes and Ketones Using AlArEt2(THF) as Aryl Sources” J. Org. Chem. 2009, 74, 3500-3505.
Shuangliu Zhou, Da-Wei Chuang, Shih-Ju Chang, Han-Mou Gau* “Synthesis, Characterization, and Structures of Arylaluminum Reagents and Asymmetric Arylation of Aldehydes Catalyzed by a Titanium Complex of N-Sulfonylated Amino Alcohol” Tetrahedron: Asymmetry 2009, 20, 1407-1412.
Deepak B. Biradar, Shuangliu Zhou and Han-Mou Gau*. “Direct Asymmetric Catalytic Thienylaluminum Addition to Ketones: A Concise Approach to the Synthesis of (S)-Tiemonium Iodide” Org. Lett. 2009, 11, 3386-3389.
Hsu-Tang Yang, Shuangliu Zhou, Feng-Shuo Chang, Chi-Ren Chen and Han-Mou Gau* “Synthesis, Structures, and Characterizations of [ArTi(O-i-Pr)3]2 and Efficient Room-Temperature Aryl-Aryl Coupling of Aryl Bromides with [ArTi(O-i-Pr)3]2 Catalyzed by the Economic Pd(OAc)2/PCy3 System” Organometallics 2009, 28, 5715-5721.
Wan-Ting Shu, Shuangliu Zhou, Han-Mou Gau* “Palladium-Catalyzed Cross-Coupling Reaction of ArAlEt2(THF) with Aryl Bromides” Synthesis, 2009, 4075-4081. (Feature Article)
Yun Wei, Zeyan Yu, Shaowu Wang*, Shuangliu Zhou, Gaosheng Yang, Lijun Zhang, Guodong Chen, Huimin Qian, Jiaxi Fan. “Synthesis, Characterization and Catalytic Activity of Organolanthanide(II) Complexes with Heterocyclic-Functionalized Fluorenyl Ligands” J. Organomet. Chem. 2008, 693, 2263-2270.
Shao-wu Wang,* Hui-min Qian, Wei Yao, Li-jun Zhang, Shuang-liu Zhou, Gao-sheng Yang., Xian-cui Zhu, Jia-xi Fan, Yu-yu Liu, Guo-dong Chen, Hai-bin Song. “ Synthesis of rare earth metal complexes incorporating amido and enolate mixed ligands: Characterization and reactivity” Polyhedron 2008, 27, 2757-2764.
Shuangliu Zhou, Shaowu Wang*, Gaosheng Yang, Qinghai Li, Lijun Zhang, Zijian Yao, Zhangkai Zhou, and Haibin Song. “Synthesis, Structure and Diverse Catalytic Activities of Ethylenebis(indenyl)lanthanide(III) Amides on the N-H, C-H Addition to Carbodiimides and e-Caprolactone Polymerization” Organometallics 2007, 26, 3755-3761.
Shuangliu Zhou, Shaowu Wang*, Enhong Sheng, Lijun Zhang, Zeyan Yu, Xiaobing Xi, Guodong Chen, Wei Luo, and Yan Li.“Synthesis, Characterization and Catalytic Activity of Some Neodymium(III) and Ytterbium(II) and Europium(II) Complexes With Pyrrolidinyl- and Piperidinyl-Functionalized Indenyl Ligands” Eur. J. Inorg. Chem. 2007, 1519-1528.
Shaowu Wang*, Xinliang Tang, Andres Vega, Jean-Yves Saillard, Shuangliu Zhou, Gaosheng Yang, Wei Yao, and Yun Wei. “Coordination and Reactivity Diversity of N-Piperidineethyl- Functionalized Indenyl Ligands: Synthesis, Structure, Theoretical Calculation, and Catalytic Activity of Organolanthanide Complexes with the Ligands”. Organometallics 2007, 26, 1512-1522.
Qinghai Li, Shaowu Wang*, Shuangliu Zhou, Gaosheng Yang, Xiancui Zhu, Yuyu Liu. “Highly Atom Efficient Guanylation of both Aromatic and Secondary Amines Catalyzed by Simple Lanthanide Amides” J. Org. Chem. 2007, 72, 6763-6767.
Shaowu Wang*, Shaoyin Wang, Shuangliu Zhou, Gaosheng Yang,; Wei Luo, Nan Hu, Zhihong Zhou, Haibin Song. “Synthesis, characterization, and catalytic activity of divalent organolanthanide complexes with new tetrahydro-2H-pyranyl-functionlized indenyl ligands”. J. Organomet. Chem. 2007, 692, 2099.
Shaowu Wang*, Xinliang Tang, Andres Vega, Jean-Yves Saillard, Shuangliu Zhou, Gaosheng Yang, Zixiang Huang. “Experimental and Theoretical Evidence for the First Example of an Organolanthanide(II) Compound Having an Indenyl Ligand Bonded to the Metal through the Benzo Ring in h4 Hapticity”. Organometallics 2006, 25, 2399-2401.
Lijun Zhang, Shaowu Wang*, Shuangliu Zhou, Gaosheng Yang, and Enhong Sheng. “Cannizzaro-Type Disproportionation of Aromatic Aldehydes to Amides and Alcohols by Using Either a Stoichiometric Amount or a Catalytic Amount of Lanthanide Compounds” J. Org. Chem. 2006, 71, 3149-3153.
Lijun Zhang, Shaowu Wang*, Enhong Sheng and Shuangliu Zhou. “A solvent-free synthesis of a, a￠ -bis(substituted benzylidene) cycloalkanones catalyzed by lanthanide amides [(Me3Si)2N]3Ln(m- Cl)Li(THF)3 under microwave irradiation”, Green Chem., 2005, 7, 683-686.
FENG Qi-Qing, ZHOU Shuang-Liu, LI Yi-Mei, WANG Shao-Wu*, SHENG En-Hong, HUANG Zi-Xian. “Synthesis and Crystal Structure of {h5:h1-[(2-Methoxyphenyl)-isopropyl]-indenyl}(di- methoxyethylene)lithium” Chinese J. Struct. Chem. 2005, 24, 1046-1048.
Enhong Sheng, Shuangliu Zhou, Shaowu Wang*, Gaosheng Yang, Yongyong Wu, Yan Feng, Lili Mao, and Zixiang Huang. “Homolysis of the Ln-N (Ln = Yb, Eu) Bond: Synthesis, Structure, and Catalytic Activity of Ytterbium(II) and Europium(II) Complexes Having (Dimethylamino)propyl- and (Dimethylamino)ethyl-Functional- ized Indenyl Ligands” Eur. J. Inorg. Chem. 2004, 2923.
Kehua Zhang, Wu Zhang, Shaowu Wang*, Enhong Sheng, Gaosheng Yang, Meihua Xie, Shuangliu Zhou, Yan Feng, Lili Mao, and Zixiang Huang, “Homolysis of the Ln-N (Ln = Yb, Eu) bond. Synthesis, structural characterization and catalytic activity of ytterbium(II) and europium(II) complexes with methoxyethyl functionalized indenyl ligands” Dalton Transactions 2004, 1029-1037.
XIE, Mei-Hua, LIU, Xin-Yuan, LIU, Li, WU, Yong-Yong, WANG, Shao-Wu*, ZHOU, Shuang-Liu, SHENG, En-Hong, YANG, Gao-Sheng, HUANG, Zi-Xiang, “Synthesis, Structure and Catalytic Activity Comparison of Tris- and Tetracoordinated Lanthanide Amides” Chinese Journal of Chemistry 2004, 22, 678-682.
Shaowu Wang*, Shuangliu Zhou, Enhong Sheng, Meihua Xie, Kehua Zhang, Lin Cheng, Yan Feng, Lili Mao, and Zixiang Huang, “Homolysis of the Eu-N Bond. “Synthesis, Structural Characterization, and Catalytic Activity of Novel Europium(II) Complexes” Organometallics, 2003, 22, 3546-3552.
Shuangliu Zhou, Shaowu Wang*, Gaosheng Yang, Xinyuan Liu, Enhong Sheng, Kehua Zhang, Lin Cheng, Zixiang Huang. “Synthesis, structure, and catalytic activity of tetracoordinate lanthanide amides [(Me3Si)2N]3Ln(m-Cl)Li(THF)3 (Ln = Nd, Sm, Eu)” Polyhedron, 2003, 22, 1019-1024.
Enhong Sheng, Shaowu Wang*, Gaosheng Yang, Shuangliu Zhou, Lin Cheng, Kehua Zhang, Zixiang Huang. “A New Heteroatom Coordination Promoted Homolysis of the Yb-N Bond. Synthesis and Structural Characterization of a New Class of Ytterbium(II) and Ytterbium(III) Complexes with Amido and Indenyl Ligands and Catalytic Activities of Ytterbium(II) Complexes” Organometallics 2003, 22, 684.
楊高升, 盛恩宏, 程林, 周雙六, 孫益民, 王紹武*, “含茂基稀土金屬有機(jī)絡(luò)合物催化劑在有機(jī)合成中的應(yīng)用”, 中國(guó)稀土學(xué)報(bào), 2002, 20, 97–106.

會(huì)議報(bào)告
Shuangliu Zhou and Han-Mou Gau*, “Application of the Aluminum Reagents in Enantioselective Arylation of Aldehydes”, 第五屆海峽兩岸生物無機(jī)與材料研討會(huì)。2008年7月，臺(tái)南，墻報(bào)。
周雙六，王紹武*，“含哌啶雜環(huán)取代茚基稀土金屬配合物的合成及其催化活性研究”，第十四屆全國(guó)金屬有機(jī)化學(xué)學(xué)術(shù)討論會(huì)。2006年10月，蘇州，墻報(bào)。
周雙六，王紹武*，盛恩宏，顧家山，“內(nèi)配位控制合成外消旋橋聯(lián)茚基稀土金屬有機(jī)配合物”，第四屆全國(guó)有機(jī)化學(xué)學(xué)術(shù)討論會(huì)。2005年8月，昆明，墻報(bào)。
周雙六，湯新亮，王紹武*，盛恩宏，“稀土金屬氮鍵-均裂反應(yīng)研究：二價(jià)鐿金屬有機(jī)配合物(C9H5-1-R-3-CH2SiMe2NC4H8)2Yb (R = H, Me)的合成、結(jié)構(gòu)和催化活性研究”，第十三屆全國(guó)金屬有機(jī)化學(xué)學(xué)術(shù)討論會(huì)。2004年10月，北京，墻報(bào)。
周雙六，王紹武*，盛恩宏，“新型雜原子配位的稀土金屬氮鍵均裂單電子還原反應(yīng)研究：含N, N-二甲基丙基茚基稀土金屬有機(jī)配合物的合成及催化活性研究”，第十二屆全國(guó)金屬有機(jī)化學(xué)學(xué)術(shù)討論會(huì)。2002年10月，福州，墻報(bào)。
Shaowu Wang*, Shuangliu Zhou, Lin Cheng, Gaosheng Yang, Enhong Sheng, and Kehua Zhang, “Synthesis, Structure and Catalytic Activities of Sterically Crowded Tetracoordinate Lanthanide Amides [(Me3Si)3N]3Ln(m-Cl)Li(THF)3×xC7H8 (Ln = Sm, Eu, x = 1; Ln = Dy, Tm, x = 1)”, XXth Internatioanl Conference on Organometallic Chemistry, July 7-12, 2002, Corfu, Greece, Post Presentation.

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