鄭州大學(xué)化學(xué)與分子工程學(xué)院導(dǎo)師：龔軍芳 正文

　
　　姓名：龔軍芳　　職稱：副教授　　
　　學(xué)院：化學(xué)與分子工程學(xué)院　最后學(xué)歷：博士
　　主要研究方向：金屬有機化學(xué)和均相催化化學(xué)
　　
　　龔軍芳，教授、碩士生導(dǎo)師，河南省教育廳學(xué)術(shù)技術(shù)帶頭人。1992年南開大學(xué)化學(xué)系畢業(yè)；1995年獲南開大學(xué)理學(xué)碩士學(xué)位；1998年在中國科學(xué)院化學(xué)研究所獲博士學(xué)位。1999.10~2001.09在鄭州大學(xué)化學(xué)系博士后流動站工作；2001.10-2003.2在法國巴黎國家高等化學(xué)學(xué)校 (Ecole Nationale Superieure de Chimie de Paris) 從事天然產(chǎn)物Ambruticin合成新方法研究。2003年-至今在鄭州大學(xué)化學(xué)系工作。

　　主要從事金屬有機化學(xué)和均相催化化學(xué)研究，先后在Organometallics; Dalton Trans.; Tetrahedron Lett.; J. Mol. Catal. A: Chem.; J. Organomet. Chem.; Aust. J. Chem.等期刊上發(fā)表學(xué)術(shù)論文40余篇 (其中SCI收錄論文30余篇)。近年來，主持完成教育部留學(xué)回國人員科研啟動費、河南省自然科學(xué)基金、鄭州大學(xué)引進人才科研啟動費和鄭州大學(xué)校級青年骨干教師等項目；作為主要人員，參與完成2項國家自然科學(xué)基金項目和2項河南省杰出人才創(chuàng)新基金。目前主持國家自然科學(xué)基金項目1項。參與翻譯、編寫著作3部，獲專利3項。

　　Email: gongjf@zzu.edu.cn
　　聯(lián)系地址：河南省鄭州市大學(xué)北路75號鄭州大學(xué)化學(xué)系 450052

　　近年來主要論文及專利目錄：
　　1. Jun-Long Niu, Qing-Tao Chen, Xin-Qi Hao, Qing-Xiang Zhao, Jun-Fang Gong*, Mao-Ping Song*. “Diphenylprolinol-derived Symmetrical and Unsymmetrical Chiral Pincer Pd(II) and Ni(II) complexes: Synthesis via One-pot Phosphorylation/metalation Reaction and C-H Activation.” Organometallics 2010, 29(9), 2148-2156.
　　2. Ben-Shang Zhang, Wei Wang, Dan-Dan Shao, Xin-Qi Hao, Jun-Fang Gong*, Mao-Ping Song*. “Unsymmetrical Chiral PCN Pincer Palladium(II) and Nickel(II) Complexes of (Imidazolinyl)aryl Phosphinite Ligands: Synthesis via Ligand C-H Activation, Crystal Structures and Catalytic Studies.” Organometallics 2010, 29(11), 2579-2587.
　　3. Jun-Fang Gong, Yan-Hui Zhang, Mao-Ping Song*, Chen Xu. “New PCN and PCP Pincer Palladium(II) Complexes: Convenient Synthesis via Facile One-pot Phosphorylation/Palladation Reaction and Structural Characterization.” Organometallics 2007, 26(25), 6487-6492.
　　4. Li-Yuan Wu, Xin-Qi Hao, Yan-Xiao Xu, Min-Qiang Jia, Ya-Nan Wang, Jun-Fang Gong*, Mao-Ping Song*. “Chiral NCN Pincer Pt(II) and Pd(II) Complexes with 1,3-Bis(2'-imidazolinyl)benzene: Synthesis via Direct Metalation, Characterization, and Catalytic Activity in the Friedel-Crafts Alkylation Reaction.” Organometallics 2009, 28(12), 3369-3380.
　　5. Ben-Shang Zhang, Chao Wang, Jun-Fang Gong*, Mao-Ping Song*. “Facile synthesis of achiral and chiral PCN pincer palladium(II) complexes and their application in the Suzuki and copper-free Sonogashira cross-coupling reactions.” J. Organomet. Chem. 2009, 694, 2555-2561.
　　6. Xin-Qi Hao, Ya-Nan Wang, Jun-Rui Liu, Kun-Lun Wang, Jun-Fang Gong,* Mao-Ping Song*. “Unsymmetrical, oxazolinyl-containing achiral and chiral NCN pincer ligand precursors and their complexes with palladium(II).” J. Organomet. Chem. 2010, 695, 82-89.
　　7. Kai Xu, Xin-Qi Hao, Jun-Fang Gong,* Mao-Ping Song,* and Yang-Jie Wu. “Room Temperature Suzuki Reactions in Aqueous Media under Air by Palladium(II) Complexes with Pyrazole Derived Ligands.” Aust. J. Chem. 2010, 63, 315-320.
　　8. Chen Xu, Jun-Fang Gong*, Su-Fang Yue, Yu Zhu, Yang-Jie Wu*. “Tricyclohexylphosphine-cyclopalladated ferrocenylimine complexes: synthesis, crystal structures and application in Suzuki and Heck reactions.” Dalton Trans. 2006, 4730-4739.
　　9. Chen Xu, Jun-Fang Gong*, Tao Guo, Yan-Hui Zhang, Yang-Jie Wu*. “Cyclopalladated ferrocenylimine complexes with dicyclohexylphosphino- biphenyl ligands: Synthesis, crystal structures and their use as highly efficient catalysts for Suzuki reaction of aryl chlorides.” J. Mol. Catal. A: Chem. 2008, 279, 69-76.
　　10. Chen Xu, Jun-Fang Gong*, Yang-Jie Wu*. “Amination of aryl chlorides in water catalyzed by cyclopalladated ferrocenylimine complexes with commercially available monophosphinobiaryl ligands.” Tetrahedron Lett. 2007, 48, 1619-1623.
　　11. Xin-Qi Hao, Jun-Fang Gong*, Chen-Xia Du, Li-Yuan Wu,Yang-Jie Wu, Mao-Ping Song*. “Synthesis, characterization and photoluminescent properties of platinum complexes with novel bis(imidazoline) pincer ligands.” Tetrahedron Lett. 2006, 47, 5033-5036.
　　12. Chen Xu, Jun-Fang Gong*, Yan-Hui Zhang, Yu Zhu, Yang-Jie Wu*. “Synthesis, Characterization and Crystal Structures of Three cis/trans Pyridine- Cyclopalladated Ferrocenylimine Complexes, and Their Catalysis in Suzuki Reactions.” Aust. J. Chem. 2007, 60, 190-195.
　　13. Jun-Fang Gong*, Xin-Heng Fan, Chen Xu, Jin-Lei Li, Yang-Jie Wu*, Mao-Ping Song. “New cycloplatinated complexes with 2-arylimidazolines: synthesis, crystal structures and photophysical properties.” J. Organomet. Chem. 2007, 692, 2006-1013.
　　14. Junfang Gong, Guangyu Liu, Chenxia Du, Yu Zhu, Yangjie Wu*. “Efficient Suzuki coupling of aryl chlorides catalyzed by tricyclohexylphosphine adducts of cyclopalladated ferrocenylimines.” J. Organomet. Chem. 2005, 690(17), 3963-3969.
　　15. Chen Xu, Jun-Fang Gong*, Mao-Ping Song, Yang-Jie Wu*. “Catalysis of the coupling reaction of aryl chlorides with bis(pinacolato)diboron by tricyclohexylphosphine- cyclopalladated ferrocenylimine complexes.” Transition Met. Chem. 2009, 34, 175-179.
　　16. Xin-Qi Hao, Fang Liu, Bi Zhang, Mei-Ling Jiang, Jun-Fang Gong, Mao-Ping Song*. “Cyclopalladated complexes of 2-(m-nitrophenyl)imidazolines: synthesis, characterization and catalytic activity in the Suzuki reaction under mild conditions.” Transition Met. Chem. 2010, 35, 271-277.
　　17. Xin-Qi Hao, Jun-Fang Gong*, Wen-Tao Song, Yang-Jie Wu, Mao-Ping Song*. “Synthesis and crystal structures of mono-, bis- as well as tris-mercurated complexes with ferrocenylazines.” Inorg. Chem. Commun. 2007, 10, 371-375.
　　18. Jun-Fang Gong*, Chen Xu, Yan-Hui Zhang, Yu Zhu, Yang-Jie Wu*. “Synthesis, characterization and crystal structures of two cis/trans pyridine-cyclopalladated ferrocenylimine complexes.” Transit. Metal Chem. 2007, 32, 1000-1004.
　　19. GONG Jun-fang *, ZHANG Yan-hui, FAN Xin-heng, WANG Da-wei, SONG Mao-ping, WU Yang-jie. “Synthesis, Structural Characterization of Ferrocenyl Iminophosphines and Amidophosphines as Well as Their Application in the Suzuki Reaction.” Chem. Res. Chinese U. 2007, 23(6), 683-687.
　　20. Jun-Fang Gong*, Da-Wei Wang, Yan-Hui Zhang, Yu Zhu, Yang-Jie Wu*. “Synthesis and Structural Characterization of Mercury(II) Complexes with a Novel Ferrocenyliminophosphine.” Inorg. Chim. Acta 2006, 359(7), 2115-2120.
　　21. Chen Xu, Jun-Fang Gong, Yan-Hui Zhang, Yu Zhu, Chen-Xia Du, Yang-Jie Wu. “Synthesis, characterization and crystal structures of a novel 1,1’-bisferrocenylimine and its monocyclopalladated derivative.” Inorg. Chem. Commun. 2006, 9, 456-459.
　　22. Ling-Zhi Du, Jun-Fang Gong*, Chen Xu, Yu Zhu, Yang-Jie Wu, Mao-Ping Song*. “Synthesis and structures of novel diastereomeric cyclopalladated ferrocenylimines derived from chiral b-amino alcohols.” Inorg. Chem. Commun. 2006, 9, 410-414.
　　23. Ling-Zhi Du, Jun-Fang Gong*, Yu Zhu, Yang-Jie Wu, Mao-Ping Song*. “Synthesis, characterization and the crystal structures of novel achiral and chiral a-ferrocenyl a-aminophosphine oxides.” Inorg. Chem. Commun. 2006, 9, 529-532.
　　24. Junfang Gong, Guangyu Liu, Yu Zhu, Chenxia Du, Maoping Song, Yangjie Wu*. “Synthesis, Characterization and Catalytic Activity in Suzuki Reaction of Cyclopalladated Ferrocenylimine Tri- phenylphosphine complexes.” Chem. J. Chin. Univ. 2006, 27(7), 1266-1271.
　　25. Junfang Gong, Chen Xu, Yangjie Wu. “Transition-Metal Catalyzed α-Arylation of Carbonyl Derivatives and Compounds with Acidic Hydrogen.” Progress in Chem. 2006, 18(6), 752-760.
　　26. Junfang Gong, Eric Bonfand, Eric Brown, Gilles Dujardin, Véronique Michelet and Jean-Pierre Genêt. “Remarkable stereocontrol in the synthesis of 1,2,3,5-tetrasubstituted tetrahydropyrans via an asymmetric heterocycloaddition of a ketone-derived enol ether. ” Tetrahedron Lett. 2003, 44(10), 2141-2144.
　　27. 龔軍芳，吳養(yǎng)潔，徐晨. “環(huán)鈀化二茂鐵亞胺-氨基膦配合物及其應(yīng)用.” 專利號：ZL 2006 1 0048594.9
　　28. 宋毛平，龔軍芳，郝新奇，武利園，汪亞男，吳養(yǎng)潔. “手性和非手性雙咪唑啉基苯類化合物及合成方法.” 專利號：ZL 2007 1 0053911.0
　　29. 宋毛平，郝新奇，龔軍芳，林昆華，張碧，李玉江. “鉗形雙咪唑啉鈀化合物及其在Suzuki反應(yīng)中的應(yīng)用.” 專利號：200710054070.5

　　參與編寫、翻譯的著作目錄：
　　1、現(xiàn)代有機反應(yīng) 胡躍飛 林國強主編 第五卷《金屬催化反應(yīng)》 撰寫《傅-克反應(yīng)》一章 2008.12 化學(xué)工業(yè)出版社 ISBN 978-7-122-03784-8
　　2、有機立體化學(xué)導(dǎo)論（譯著）國外名校名著系列 2007.1 化學(xué)工業(yè)出版社 ISBN 978-7-5025-8940-0 翻譯第13-16章等
　　3、有機化學(xué)學(xué)習(xí)指導(dǎo) 國家理科基地名牌課程建設(shè)參考書 2008.1 鄭州大學(xué)出版社 ISBN 978-7-81106-743-9 參編

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